Publications

The protection of superconducting qubits from certain noise sources often comes at the cost of increased sensitivity to other decoherence channels. Here, we explore a route to avoid this tradeoff by encoding quantum information in quantum states of a transmon entangled with the spin of a trapped Andreev quasiparticle. We term such devices spinmons. We lift the spinmon Kramers degeneracy by introducing a Zeeman field and develop two routes for full qubit control via electrostatic gates and an AC flux drive, providing multiple directions for experimental implementations. Finally, we compute coherence times and verify the qubit robustness against flux and charge noise sources.

Planar germanium heterostructures are promising hosts for hybrid quantum devices due to their compatibility with superconductors, low material disorder, and relaxed fabrication constraints. Also, the potentially low density of nuclear spins and strong spin-orbit interaction make germanium attractive for coherent spin physics. However, recent microwave spectroscopy experiments were unable to resolve a spin-splitting of bound states in germanium Josephson junctions, the prerequisite for defining and controlling Andreev spin qubits. Here, we argue that compressive strain is the key mechanism suppressing spin splitting in current devices. Furthermore, we propose unstrained and tensile-strained heterostructures, fully compatible with state-of-the-art growth technology, that significantly enhance the relevant spin-orbit effect. By numerically simulating ballistic Josephson junctions, we predict spin splittings comfortably in the GHz range, more than 2 orders of magnitude larger than compressively strained cases, and all-electric quantum gates in a hundred nanoseconds. Our results establish strain engineering as a key design principle for realizing Andreev spin qubits in germanium-based devices.

We theoretically investigate loopless multiterminal hybrid superconducting devices at odd fermion parity with time-reversal symmetry. We find that the energy-phase relationship has a double minimum corresponding to opposite windings of the superconducting phases. Spin-orbit coupling adds multi-axial spin splittings, which contrasts with two-terminal devices where spin dependence is uniaxial. Capacitive shunting localizes quantum circuit states in the wells and exponentially suppresses their splitting. For weak spin-orbit strength, the system has a four-dimensional spin-chirality low-energy subspace which can be universally controlled with electric fields only.

To observe Majorana bound states, and especially to use them as a qubit, requires careful optimization of competing quality metrics. We systematically compare Majorana quality in proximitized semiconductor nanowires and quantum dot chains. Using multi-objective optimization, we analyze the fundamental trade-offs between topological gap and localization length, two key metrics that determine MBS coherence and operational fidelity. We demonstrate that these quantities cannot be simultaneously optimized in realistic models, creating Pareto frontiers that define the achievable parameter space. Our results show that QD chains achieve both comparable quality as nanowires and a regime with a much shorter localization length, making them particularly promising for near-term quantum computing applications where device length and disorder are limiting factors.

Kondo physics and heavy-fermion behavior have been predicted and observed in moiré materials. The electric tunability of moiré materials allows an in-situ study of Kondo lattices' phase diagrams, which is not possible with their intermetallic counterparts. However, moiré platforms rely on twisting, which introduces twisting angle disorder and undesired buckling. Here we propose device layouts for one- and two-dimensional gate-defined superlattices in Bernal bilayer graphene where localized states couple to dispersive valley-helical modes. We show that, under electronic interactions, these superlattices are described by an electrically-tunable Kondo-Heisenberg model.

The easily accessible experimental signatures of Majorana modes are ambiguous and only probe topology indirectly: for example, quasi-Majorana states mimic most properties of Majoranas. Establishing a correspondence between an experiment and a theoretical model known to be topological resolves this ambiguity. Here we demonstrate that already theoretically determining whether a finite system is topological is by itself ambiguous. In particular, we show that the scattering topological invariant – a probe of topology most closely related to transport signatures of Majoranas – has multiple biases in finite systems. For example, we identify that quasi-Majorana states also mimic the scattering invariant of Majorana zero modes in intermediate-sized systems. We expect that the bias due to finite size effects is universal, and advocate that the analysis of topology in finite systems should be accompanied by a comparison with the thermodynamic limit. Our results are directly relevant to the applications of the topological gap protocol.

We demonstrate that Andreev modes that propagate along a transparent Josephson junction have a perfect transmission at the point where three junctions meet. The chirality and the number of quantized transmission channels is determined by the topology of the Fermi surface and the vorticity of the superconducting phase differences at the trijunction. We explain this chiral adiabatic transmission (CAT) as a consequence of the adiabatic evolution of the scattering modes both in momentum and real space. The dispersion relation of the junction then separates the scattering trajectories by introducing inaccessible regions of phase space. We expect that CAT is observable in nonlocal conductance and thermal transport measurements. Furthermore, because it does not rely on particle-hole symmetry, CAT is also possible to observe directly in metamaterials.

Direct dipole coupling between a two-level system and a bosonic mode describes the interactions present in a wide range of physical platforms. In this work, we study a coupling that is mixed between two pairs of quadratures of a bosonic mode and a spin. In this setting, we can suppress the dispersive shift while retaining a nonzero Kerr shift, which remarkably results in a cubic relationship between shot noise dephasing and thermal photons in the oscillator. We demonstrate this configuration with a simple toy model, quantify the expected improvements to photon shot-noise dephasing of the spin, and describe an approach to fast qubit readout via the Kerr shift. Further, we show how such a regime is achievable in superconducting circuits because magnetic and electric couplings can be of comparable strength, using two examples: the Cooper pair transistor and the fluxonium molecule.

Despite many reports of valley-related phenomena in graphene and its multilayers, current transport experiments cannot probe valley phenomena without the application of external fields. Here we propose a gate-defined valley splitter as a direct transport probe for valley phenomenon in graphene multilayers. First, we show how the device works, its magnetotransport response, and its robustness against fabrication errors. Secondly, we present two applications for valley splitters: (i) resonant tunneling of quantum dots probed by a valley splitter shows the valley polarization of dot levels; (ii) a combination of two valley splitters resolves the nature of order parameters in mesoscopic samples.

The achievement of valley-polarized electron currents is a cornerstone for the realization of valleytronic devices. Here, we report on ballistic coherent transport experiments where two opposite quantum point contacts (QPCs) are defined by electrostatic gating in a bilayer graphene (BLG) channel. By steering the ballistic currents with an out-of-plane magnetic field we observe two current jets, a consequence of valley-dependent trigonal warping. Tuning the BLG carrier density and number of QPC modes (m) with a gate voltage we find that the two jets are present for m=1 and up to m=6, indicating the robustness of the effect. Semiclassical simulations which account for size quantization and trigonal warping of the Fermi surface quantitatively reproduce our data without fitting parameters, confirming the origin of the signals. In addition, our model shows that the ballistic currents collected for non-zero magnetic fields are valley-polarized independently of m, but their polarization depends on the magnetic field sign, envisioning such devices as ballistic current sources with tuneable valley-polarization.

We propose a practical implementation of a universal quantum computer that uses local fermionic modes (LFM) rather than qubits. The device layout consists of quantum dots tunnel coupled by a hybrid superconducting island and a tunable capacitive coupling between the dots. We show that coherent control of Cooper pair splitting, elastic cotunneling, and Coulomb interactions allows us to implement the universal set of quantum gates defined by Bravyi and Kitaev. Due to the similarity with charge qubits, we expect charge noise to be the main source of decoherence. For this reason, we also consider an alternative design where the quantum dots have tunable coupling to the superconductor. In this second device design, we show that there is a sweetspot for which the local fermionic modes are charge neutral, making the device insensitive to charge noise effects. Finally, we compare both designs and their experimental limitations and suggest future efforts to overcome them.

We report on multiterminal measurements in a ballistic bilayer graphene (BLG) channel where multiple spin and valley-degenerate quantum point contacts (QPCs) are defined by electrostatic gating. By patterning QPCs of different shapes and along different crystallographic directions, we study the effect of size quantization and trigonal warping on the transverse electron focusing (TEF) spectra. Our TEF spectra show eight clear peaks with comparable amplitude and weak signatures of quantum interference at the lowest temperature, indicating that reflections at the gate-defined edges are specular and transport is phase coherent. The temperature dependence of the scattering rate indicates that electron-electron interactions play a dominant role in the charge relaxation process for electron doping and temperatures below 100 K. The achievement of specular reflection, which is expected to preserve the pseudospin information of the electron jets, is promising for the realization of ballistic interconnects for new valleytronic devices.

Caroli-de Gennes-Matricon (CdGM) states are localized states with a discrete energy spectrum bound to the core of vortices in superconductors. In topological superconductors, CdGM states are predicted to coexist with zero-energy, chargeless states widely known as Majorana zero modes (MZMs). Due to their energy difference, current experiments rely on scanning tunneling spectroscopy methods to distinguish between them. This work shows that electrostatic inhomogeneities can push trivial CdGM states arbitrarily close to zero energy in non-topological systems where no MZM is present. Furthermore, the BCS charge of CdGM states is suppressed under the same mechanism. Through exploration of the impurity parameter space, we establish that these two phenomena generally happen in consonance. Our results show that energy and charge shifts in CdGM may be enough to imitate the spectroscopic signatures of MZMs even in cases where the estimated CdGM level spacing (in the absence of impurities) is much larger than the typical experimental level broadening.

We theoretically predict spatial separation of spin-polarized ballistic currents in transition metal dichalcogenides (TMDs) due to trigonal warping. We quantify the effect in terms of spin polarization of charge carrier currents in a prototypical 3-terminal ballistic device where spin-up and spin-down charge carriers are collected by different leads. We show that the magnitude of the current spin polarization depends strongly on the charge carrier energy and the direction with respect to crystallographic orientations in the device. We study the (negative) effect of lattice imperfections and disorder on the observed spin polarization. Our investigation provides an avenue towards observing spin discrimination in a defect-free time reversal-invariant material.

We simulate a hybrid superconductor-graphene device in the quantum Hall regime to identify the origin of downstream resistance oscillations in a recent experiment [Zhao et. al. Nature Physics , (2020)]. In addition to the previously studied Mach-Zehnder interference between the valley-polarized edge states, we consider disorder-induced scattering, and the previously overlooked appearance of the counter-propagating states generated by the interface density mismatch. Comparing our results with the experiment, we conclude that the observed oscillations are induced by the interfacial disorder, and that lattice-matched superconductors are necessary to observe the alternative ballistic effects.

We study the electronic properties of InAs/EuS/Al heterostructures as explored in a recent experiment [S. Vaitiekenas et al., Nat. Phys. (2020)], combining both spectroscopic results and microscopic device simulations. In particular, we use angle-resolved photoemission spectroscopy to investigate the band bending at the InAs/EuS interface. The resulting band offset value serves as an essential input to subsequent microscopic device simulations, allowing us to map the electronic wave function distribution. We conclude that the magnetic proximity effects at the Al/EuS as well as the InAs/EuS interfaces are both essential to achieve topological superconductivity at zero applied magnetic field. Mapping the topological phase diagram as a function of gate voltages and proximity-induced exchange couplings, we show that the ferromagnetic hybrid nanowire with overlapping Al and EuS layers can become a topological superconductor within realistic parameter regimes, and that the topological phase can be optimized by external gating. Our work highlights the need for a combined experimental and theoretical effort for faithful device simulation.

Flat bands emerging in buckled monolayer graphene superlattices have been recently shown to realize correlated states analogous to those observed in twisted graphene multilayers. Here, we demonstrate the emergence of valley topology driven by competing electronic correlations in buckled graphene superlattices. We show, both by means of atomistic models and a low-energy description, that the existence of long-range electronic correlations leads to a competition between antiferromagnetic and charge density wave instabilities, that can be controlled by means of screening engineering. Interestingly, we find that the emergent charge density wave has a topologically non-trivial electronic structure, leading to a coexistent quantum valley Hall insulating state. In a similar fashion, the antiferromagnetic phase realizes a spin-polarized quantum valley-Hall insulating state. Our results put forward buckled graphene superlattices as a new platform to realize interaction-induced topological matter.

In the present work, we investigated the electronic and elastic properties in equilibrium and under strain of the type-II Dirac semimetal NiTe$_2$ using density functional theory (DFT). Our results demonstrate the tunability of Dirac nodes' energy and momentum with strain and that it is possible to bring them closer to the Fermi level, while other metallic bands are supressed. We also derive a minimal 4-band effective model for the Dirac cones which accounts for the aforementioned strain effects by means of lattice regularization, providing an inexpensive way for further theoretical investigations and easy comparison with experiments. On an equal footing, we propose the static control of the electronic structure by intercalating alkali species into the van der Waals gap, resulting in the same effects obtained by strain-engineering and removing the requirement of in situ strain. Finally, evaluating the wavefunction's symmetry evolution as the lattice is deformed, we discuss possible consequences, such as Liftshitz transitions and the coexistence of type-I and type-II Dirac cones, thus motivating future investigations.

Electronic correlations stemming from nearly flat bands in van der Waals materials have demonstrated to be a powerful playground to engineer artificial quantum matter, including superconductors, correlated insulators and topological matter. This phenomenology has been experimentally observed in a variety of twisted van der Waals materials, such as graphene and dichalcogenide multilayers. Here we show that spontaneously buckled graphene can yield a correlated state, emerging from an elastic pseudo Landau level. Our results build on top of recent experimental findings reporting that, when placed on top of hBN or NbSe$_2$ substrates, wrinkled graphene sheets relax forming a periodic, long-range buckling pattern. The low-energy physics can be accurately described by electrons in the presence of a pseudo-axial gauge field, leading to the formation of sublattice-polarized Landau levels. Moreover, we verify that the high density of states at the zeroth Landau level leads to the formation of a periodically modulated ferrimagnetic groundstate, which can be controlled by the application of external electric fields. Our results indicate that periodically strained graphene is a versatile platform to explore emergent electronic states arising from correlated elastic Landau levels.

It was recently proposed that the interface between a graphene nanoribbon in the canted antiferromagnetic quantum Hall state and a s-wave superconductor may present topological superconductivity, resulting in the appearance of Majorana zero modes. However, a description of the low-energy physics in terms of experimentally controllable parameters was still missing. Starting from a mean-field continuum model for graphene in proximity to a superconductor, we derive the low-energy effective Hamiltonian describing the interface of this heterojunction from first principles. A comparison between tight-binding simulations and analytical calculations with effective masses suggests that normal reflections at the interface must be considered in order to fully describe the low-energy physics.

Transition metal dichalcogenides (TMDs) usually show simple structures, however, with interesting properties. Recently some TMDs have been pointed out as type-II Dirac semimetals. In the present work, we investigate the physical properties of a new candidate for type-II Dirac semimetal and investigate the effect of titanium doping on physical properties of Ti-doped single crystalline samples of NiTe2. It was found that this compound shows a superconducting properties with a critical temperature close to 4.0 K. Interestingly, applied pressures up to 1.3 GPa have no effect upon the superconducting state. Density Functional Theory (DFT) calculations demonstrate the presence of a Dirac cone in the band structure of NiTe2 literature when Spin-Orbit Coupling (SOC) is included, which is in agreement with a recent report for this compound. Also, our calculations demonstrate that Ti suppresses the formation of these non-trivial states.

The physical properties of the Zr$_5$Pt$_3$ compound with interstitial carbon in hexagonal D8$_8$-structure was investigated. A set of macroscopic measurements reveal a bulk superconducting at approximately 7 K for Zr$_5$Pt$_3$C$_0.3$ close to Zr$_5$Pt$_3$, also with a correlate anomalous resistivity behavior. However, both the signatures of strong electron-electron interaction, and the electronic contribution to specific heat, increase dramatically with the C doping. For the first time the x-ray photoelectron spectra compared with DFT/PWLO calculations of electronic structure show a complex Fermi surface with high density of states for Zr$_5$Pt$_3$. Also results show the signature of unconventional superconductivity. Indeed, was observed an unusual behavior for lower and upper critical field diagrams of Zr$_5$Pt$_3$C$_0.3$. The temperature dependence of penetration length and electronic contribution to specific heat suggests that electronic pairing deviates of $s$-wave the BCS scenario.

Majorana fermions are particles identical to their antiparticles proposed theoretically in 1937 by Ettore Majorana as real solutions of the Dirac equation. Alexei Kitaev suggested that Majorana particles should emerge in condensed matter systems as zero mode excitations in one-dimensional p-wave superconductors, with possible applications in quantum computation due to their non-abelian statistics. The search for Majorana zero modes in condensed matter systems led to one of the first realistic models based in a semiconductor nanowire with high spin-orbit coupling, induced superconducting s-wave pairing and Zeeman splitting. Soon, it was realized that size-quantization effects should generate subbands in these systems that could even allow the emergence of more than one Majorana mode at each edge, resulting in a zero bias peak on the differential conductance with a different shape from the predicted by simplified theoretical models. In this work, we provide a connection between a finite-size nanowire with two occupied subbands and a 2-band Kitaev chain and discuss the advantage of an one-dimensional model to understand the phenomenology of the system, including the presence of a hidden chiral symmetry and its similarity with a spinfull Kitaev chain under a magnetic field.

Realistic implementations of the Kitaev chain require, in general, the introduction of extra internal degrees of freedom. In the present work, we discuss the presence of hidden BDI symmetries for free Hamiltonians describing systems with an arbitrary number of internal degrees of freedom. We generalize results of a spinfull Kitaev chain to construct a Hamiltonian with $n$ internal degrees of freedom and obtain the corresponding hidden chiral symmetry. As an explicit application of this generalized result, we exploit by analytical and numerical calculations the case of a spinful 2-band Kitaev chain, which can host up to 4 Majorana bound states. We also observe the appearence of minigap states, when chiral symmetry is broken.

Magnesium diboride superconductors are important materials used for practical applications around the world, due to the properties and to the low price of the precursor elements, as well as the possibility to apply the material in magnets and electronic devices, operating with cryocoolers. In the present work, a methodology to optimize the properties of MgB 2 bulk superconductors is described. The method uses the addition of an organic carbon source (stearic acid, C$_18$H$_36$O$_2$), due to the homogeneous distribution of the doping material in the matrix, before final chemical reaction. The procedure was developed using high-energy ball milling to mix the precursor powders and performing heat treatment in a hot isostatic press, to improve the densification and grain connectivity. As a result, the critical current density enhanced around 600 times at 3T, when compared to the pure MgB$_2$ samples produced using the same approach.

The relatively high critical temperature and upper critical field and the low cost of the raw materials are the main reasons to consider MgB2 as a very promising material for superconducting applications. Improving the relatively low flux pinning in this material is important to optimize the critical current density of MgB2 superconducting wires, tape, and bulks. Adding secondary phases in a controlled way can create new pinning centers and improve the critical current density. This paper describes a methodology to produce MgB2 powders containing additions of diborides (VB2) and carbon (carbon nanotubes) that can also improve the upper critical field. MgB2 powders with these additions were used to produce Cu-Nb-MgB2 and CuNi-Nb-MgB2 multifilamentary wires. Characterization of the samples showed the microstructure, phase distribution, and microhardness in their cross sections after mechanical deformation, along with some superconducting properties and characteristics.